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Lanthanides: Chemistry and Use in Organic Synthesis
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Artikel-Nr:
9783642084195
Veröffentl:
2010
Einband:
Paperback
Erscheinungsdatum:
05.12.2010
Seiten:
320
Autor:
Shu Kobayashi
Gewicht:
487 g
Format:
235x155x18 mm
Serie:
2, Topics in Organometallic Chemistry
Sprache:
Englisch
Beschreibung:
The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistry is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.
With contributions by numerous experts
Principles in Organolanthanide Chemistry.- Lanthanide Triflate-Catalyzed Carbon-Carbon Bond-Forming Reactions in Organic Synthesis.- Lanthanide- and Group 3 Metallocene Catalysis in Small Molecule Synthesis.- Influence of Solvents or Additives on the Organic Chemistry Mediated by Diiodosamarium.- Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts for the Asymmetric Formation of C-C, C-O, and C-P Bonds.- Reactions of Ketones with Low-Valent Lanthanides: Isolation and Reactivity of Lanthanide Ketyl and Ketone Dianion Complexes.- Organo Rare Earth Metal Catalysis for the Living Polymerizations of Polar and Nonpolar Monomers.- Polymer-Supported Rare Earth Catalysts Used in Organic Synthesis.