Zinc Catalysis: Applications in Organic Synthesis

Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

INTRODUCTION: ZINC CATALYSTS FOR ORGANIC TRANSFORMATIONSZINC-CATALYZED REDUCTIONS OF UNSATURATED COMPOUNDSIntroductionHydrosilylation of Unsaturated CompoundsHydrogenationTransfer Hydrogenation of Unsaturated CompoundsConcluding RemarksZINC-CATALYZED OXIDATION REACTIONSIntroductionOxidative Transformation of AlkenesOxidative Transformation of AldehydesOxidative Transformation of C?X Bonds (X=O, N, and S)Oxidative Functionalization of sp3 C?H BondsOther Oxidative Reactions with Redox-Active LigandsSummary and OutlookZINC-CATALYZED FRIEDEL-CRAFTS REACTIONSIntroductionFriedel-Crafts AcylationFriedel-Crafts AlkylationsConclusionsZINC-CATALYZED HYDROAMINATION REACTIOSIntroductionInorganic Zinc Salts as CatalystsAminotroponiminate Zinc Complexes as CatalystsOther Zinc Organometallic Compounds as CatalystsDouble Metal Cyanide CatalystsSummaryZINC-CATALYZED C-C BOND FORMATIONIntroductionZinc-Catalyzed Aldol-Type ReactionsZinc-Catalyzed Cycloaddition ReactionsZinc-Catalyzed Addition of Organometallic Reagents to Carbonyl and Related CompoundsZinc-Catalyzed Cross-Coupling ReactionsRadical Reactions Involving Catalytic Amounts of ZincZinc-Catalyzed Reactions through Alkyne ActivationZinc-Catalyzed Cyclopropanation ReactionsOther Zinc-Catalyzed ReactionsSummary and OutlookZINC-CATALYZED C-N AND C-O BOND FORMATION REACTIONSIntroductionZinc-Catalyzed C-N Bond Formation ReactionsZinc-Catalyzed C-O Bond Formation ReactionsSummary and ConclusionsZINC-CATALYZED TRANSFORMATIONS OF CARBON DIOXIDEIntroductionZinc Catalysts for the Copolymerization of Epoxides and CO2Zinc-Catalyzed Synthesis of Cyclic Carbonates Utilizing Carbon Dioxide as a Chemical FeedstockSummaryZINC-CATALYZED DEPOLYMERIZATION REACTIONSIntroductionZinc-Catalyzed Depolymerization of PolyethersZinc-Catalyzed Depolymerization of PolyestersZinc-Catalyzed Depolymerization of SiliconesSummaryAPPLICATIONS OF ZINC-PROMOTED REACTION IN TOTAL SYNTHESISIntroductionZinc-Promoted Reactions without LigandsZinc-Mediated Reactions with LigandsOther Zinc-Promoted ReactionsAPPLICATION OF ORGANOZINC REAGENTS IN OXIDATIVE COUPLING REACTIONSIntroductionOxidative Coupling between Zinc Reagents and C(sp) NucleophilesOxidative Coupling between Organozinc Reagents and C(sp2) NucleophilesOxidative Coupling between Organozinc Reagents and C(sp3) NucleophilesOxidative Coupling between Organozinc Reagents and Heteroatom NucleophilesConclusionIndex