Chemical Physics of Intercalation II

This volume provides a record of the second ASI on the subject "Chemical Physics of Intercalation", which was patterned after its highly successful July 1987 predecessor. A growing community of chemists, physicists and materials scientists has come to appreciate the utility of extending the intercalation concept to generic guest-host compounds and solid solutions. The unifying themes are the complex phase equilibria which result from the competition between repulsive and attractive interactions between and within the guest and host substructures, the tunability of properties by control of guest concentration and superlattice periodicity, and the broad spectrum of potential applications which these materials may provide. The success of this initiative may be judged by noting the enlarged scope of materials covered in this volume as compared to its predecessor. The present volume covers the spectrum from 3-dimensional oxides, 2-dimensional classical layer intercalates,- dimensional doped polymers and zero-dimensional doped fullerene lattices. Hybrid systems such as polymers in layer hosts and nonporous hosts are also treated. Several chapters provide global unifying viewpoints by focussing on sold state chemical aspects, transport and optical properties, the occurrence of superconductivity, etc.

Proceedings of a NATO ASI held at the Chateau de Bonas, France, June 29-July 19, 1992

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Host Structures Modifications Induced by Intercalation/Deintercalation into Lamellar Chalcogenides.- Superconducting Intercalation Compounds of C60 and Graphite.- Conjugated Polymers in Layered Hosts: Formation of Emeraldine Salt and Polyfuran in FeOCl.- Alkali Metal Compounds of C60: an Intercalation Perspective.- Staging in Intercalated Graphites, Polymers and Fullerenes.- Synthesis and Reaction Chemistry of Layered Oxides with Perovskite Related Structures.- Size-Mismatch Effects in Alloys.- The Structure, Morphology and Layer Rigidity of Clay Intercalation Compounds.- Electrochemical Spectroscopy and In-Situ Diffraction Studies of Intercalation Compounds.- Size-Mismatch Melting in Two Dimensions.- Tight-Binding Molecular Dynamics for Intercalation Chemistry.- Quantum Chemical Calculations of C60 Vibrational Frequencies and Electronic States.- Electron Correlations and Electron-Lattice Coupling in C60.- Local Oscillator Model for Superconducting Fullerenes.- Some Optical Properties of Fullerenes.- Electron Pair Transfer in A3C60.- C60 Interaction with GaAs and Bi.- Photoluminescence of Solid State Fullerenes.- Electronic Properties of MxC60 as Seen by N.M.R. and E.P.R. and Compared to Graphite Intercalation Compounds.- Magnetic Properties of Alkali Metal Intercalated Fullerides.- Electrochemical and X-Ray Diffraction Studies of the LiC60 System.- Characterization of K-Doped C60 Using Positrons.- Superconductivity and ESR in Cesium-Doped C60.- Magnetic Properties of Halogen Doped C60.- The Electromagnetic Properties of Conducting Polymers and Intercalated C60.- Domain Structures in Heavily Alkali-Metal Doped Poly(p-phenylene vinylene).- Charge Transport and Percolation in Conducting Polymers.- Synthesis, P and N Doping of Highly Oriented Polyacetylene HOPA.- Overviewon the Chemistry of Intercalation into Graphite of Binary Metallic Alloys.- Study of FeCl3 and CoCl2 Graphite Intercalation Compounds Reduced by Heavy Alkali Metal Vapor.- Non-Redox Intercalation into the MPS3 Lamellar Materials: Chemistry and Physical Properties.- Mineralomimetic Inclusion Behavior of Cadmium Cyanide Systems.- Modification of the Near Surface Properties of Layered Semiconducting Compounds by Ion Implantation.- Intercalation Pressure, Application to LixTiS2.- Intercalation by K, Cs, Ba, Pt, Si and C Atoms of the Graphite Monolayer on the Surface of Metals and its Mechanism.- Optical and Electrical Investigation of Rare Earth Substituted Y1Ba2Cu3O7-? Ceramics and Single Crystals.- Mercury Intercalation in Titanium and Tantalum Disulfides.- Li Diffusion in Stage 2 Li-Graphite Intercalation Compounds Studied with Quasielastic Neutron Scattering.- Electron Transport in Bi2Se3 Intercalated with Hydrazine and Phenyl-Hydrazine.- Infrared Spectroscopic Evidence for Mixed Valency in Cd2P2S6cobaltocene0.8.- Intercalation Complexes of Kaolinite and Ethylenediamine: Structure and Bonds with the Lattice of Two Ethylene-Diamine Conformers.- Catalytic Oxidation of Sulphide Ions on MoS2 by Intercalation Mechanism.- Synthesis and Characterization of the First Organosulfur Electron Donor Intercalates of the Metal Dichalcogenides and Dihalides.- Intercalation of Mercury into lT-TaS2 and 2H-TaS2: a combined TDPAC and X-Ray Study.- Oxidation of Synthetic Annite Mica Characterized by 57Fe Mössbauer Spectroscopy: Hydrogen De-Intercalation and Host-Layer Valence State Populations.- Specific Heat of the High Tc Organic Superconductor ?-(ET)2Cu[N(CN)2]Br.- Electrical Properties of Oxyethylene Intercalated Compounds.