Metal-Organic Framework Materials

Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: wileyonlinelibrary.com/ref/eibc

Metal-Organic Frameworks (MOFs) are crystalline compoundsconsisting of rigid organic molecules held together and organizedby metal ions or clusters. Special interests in these materialsarise from the fact that many are highly porous and can be used forstorage of small molecules, for example H2 orCO2. Consequently, the materials are ideal candidatesfor a wide range of applications including gas storage, separationtechnologies and catalysis. Potential applications includethe storage of hydrogen for fuel-cell cars, and the removal andstorage of carbon dioxide in sustainable technical processes. MOFsoffer the inorganic chemist and materials scientist a wide range ofnew synthetic possibilities and open the doors to new and excitingbasic research.Metal-Organic Frameworks Materials provides a solid basisfor the understanding of MOFs and insights into new inorganicmaterials structures and properties. The volume also reflectsprogress that has been made in recent years, presenting a widerange of new applications including state-of-the art developmentsin the promising technology for alternative fuels. Thecomprehensive volume investigates structures, symmetrysupramolecular chemistry, surface engineering, recognitionproperties, and reactions.The content from this book will be added online to theEncyclopedia of Inorganic and Bioinorganic Chemistry: href="wileyonlinelibrary.com/ref/eibc">wileyonlinelibrary.com/ref/eibc

Contributors xiSeries Preface xvVolume Preface xviiPart 1: Design and Synthesis 1Porous Coordination Polymer Nanoparticles and Macrostructures 3Julien Reboul and Susumu KitagawaNanoscale Metal-Organic Frameworks 19Kyriakos C. Stylianou, Inhar Imaz and Daniel MaspochMesoporous Metal-Organic Frameworks 39Yao Chen and Shengqian MaPorphyrinic Metal-Organic Frameworks 67Chao Zou, Min Zhao and Chuan-De WuFluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties 85Pradip Pachfule and Rahul BanerjeeSynthesis and Structures of Aluminum-Based Metal-Organic Frameworks 99Norbert StockPolyrotaxane Metal-Organic Frameworks 115Stephen J. Loeb and V. Nicholas VukoticPhotoreactive Metal-Organic Frameworks 135Anjana Chanthapally and Jagadese J. VittalEdible Metal-Organic Frameworks 159Ross Stewart ForganMechanochemical Approaches to Metal-Organic Frameworks 173Tomislav FriscicPart 2: Post-Modification 193Postsynthetic Modification of Metal-Organic Frameworks 195Andrew D. BurrowsPart 3: Properties and Applications 219Functional Magnetic Materials Based on Metal Formate Frameworks 221Ran Shang, Sa Chen, Zhe-Ming Wang and Song GaoMetal-Organic Frameworks from Single-Molecule Magnets 245Athanassios D. Katsenis, Euan K. Brechin and Giannis S. PapaefstathiouOpen Metal Sites in Metal-Organic-Frameworks 259Yabing He and Banglin ChenGas Storage in Metal-Organic Frameworks 283Muwei Zhang, Hao Li, Zachary Perry and Hong-Cai ZhouMetal-Organic Frameworks for Removal of Harmful Gases 303Jian Liu, B. Peter McGrail, Denis M. Strachan, Jun Liu, Jian Tian and Praveen K. ThallapallyAdsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials 321Debasis Banerjee, Benjamin J. Deibert, Hao Wang and Jing LiMetal Uptake in Metal-Organic Frameworks 343Michaele J. HardiePhotoreactive Properties Hosted in Metal-Organic Frameworks 363Victoria J. Richards, Thomas J. Reade, Michael W. George and Neil R. ChampnessSemiconducting Metal-Organic Frameworks 373Zhengtao XuPatterning Techniques for Metal-Organic Frameworks 387Paolo Falcaro and Mark J. StylesMetal-Organic Frameworks in Mixed-Matrix Membranes 403Harold B. Tanh Jeazet and Christoph JaniakElectrochemical Properties of Metal-Organic Frameworks 419Frédéric Jaouen and Adina MorozanApplications of Metal-Organic Frameworks to Analytical Chemistry 443Na Chang, Cheng-Xiong Yang and Xiu-Ping YanRecent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks 457Yining Huang, Jun Xu, Farhana Gul-E-Noor and Peng HePart 4: Nets 471Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks 473Subhadip Neogi, Susan Sen and Parimal K. BharadwajInterpenetration and Entanglement in Coordination Polymers 523Stuart R. BattenIndex 539