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Frontiers of Surface-Enhanced Raman Scattering
-0 %
Single Nanoparticles and Single Cells
Besorgungstitel - wird vorgemerkt | Lieferzeit: Besorgungstitel - Lieferbar innerhalb von 10 Werktagen I
Artikel-Nr:
9781118359020
Veröffentl:
2014
Erscheinungsdatum:
31.03.2014
Seiten:
336
Autor:
Yukihiro Ozaki
Gewicht:
726 g
Format:
244x165x23 mm
Sprache:
Englisch
Beschreibung:
EDITORS
YUKIHIRO OZAKI, School of Science & Technology, Kwansei Gakuin University, Japan
KATRIN KNEIPP, Department of Physics, Technical University of Denmark, Denmark
RICARDO AROCA, Department of Chemistry & Biochemistry, University of Windsor, Canada
YUKIHIRO OZAKI, School of Science & Technology, Kwansei Gakuin University, Japan
KATRIN KNEIPP, Department of Physics, Technical University of Denmark, Denmark
RICARDO AROCA, Department of Chemistry & Biochemistry, University of Windsor, Canada
A comprehensive presentation of Surface-Enhanced Raman Scattering (SERS) theory, substrate fabrication, applications of SERS to biosystems, chemical analysis, sensing and fundamental innovation through experimentation. Written by internationally recognized editors and contributors.
Relevant to all those within the scientific community dealing with Raman Spectroscopy, i.e. physicists, chemists, biologists, material scientists, physicians and biomedical scientists.
SERS applications are widely expanding and the technology is now used in the field of nanotechnologies, applications to biosystems, nonosensors, nanoimaging and nanoscience.
Relevant to all those within the scientific community dealing with Raman Spectroscopy, i.e. physicists, chemists, biologists, material scientists, physicians and biomedical scientists.
SERS applications are widely expanding and the technology is now used in the field of nanotechnologies, applications to biosystems, nonosensors, nanoimaging and nanoscience.
A comprehensive presentation of Surface-Enhanced Raman Scattering (SERS) theory, substrate fabrication, applications of SERS to biosystems, chemical analysis, sensing and fundamental innovation through experimentation. Written by internationally recognized editors and contributors.
List of Contributors xi
Preface xv
1. Calculation of Surface-Enhanced Raman Spectra Including Orientational and Stokes Effects Using TDDFT/Mie Theory QM/ED Method 1
George C. Schatz and Nicholas A. Valley
1.1 Introduction: Combined Quantum Mechanics/Electrodynamics Methods 1
1.2 Computational Details 3
1.3 Summary of Model Systems 4
1.4 Azimuthal Averaging 5
1.5 SERS of Pyridine: Models G, A, B, S, and V 6
1.6 Orientation Effects in SERS of Phthalocyanines 11
1.7 Two Particle QM/ED Calculations 13
1.8 Summary 15
Acknowledgment 16
References 16
2. Non-resonant SERS Using the Hottest Hot Spots of Plasmonic Nanoaggregates 19
Katrin Kneipp and Harald Kneipp
2.1 Introduction 19
2.2 Aggregates of Silver and Gold Nanoparticles and Their Hot Spots 21
2.2.1 Evaluation of Plasmonic Nanoaggregates by Vibrational Pumping due to a Non-resonant SERS Process 21
2.2.2 Probing Plasmonic Nanoaggregates by Electron Energy Loss Spectroscopy 24
2.2.3 Probing Local Fields in Hot Spots by SERS and SEHRS 25
2.3 SERS Using Hot Silver Nanoaggregates and Non-resonant NIR Excitation 26
2.3.1 SERS Signal vs. Concentration of the Target Molecule 26
2.3.2 Spectroscopic Potential of Non-resonant SERS Using the Hottest Hot Spots 30
2.4 Summary and Conclusions 31
References 32
3. Effect of Nanoparticle Symmetry on Plasmonic Fields: Implications for Single-Molecule Raman Scattering 37
Lev Chuntonov and Gilad Haran
3.1 Introduction 37
3.2 Methodology 38
3.3 Plasmon Mode Structure of Nanoparticle Clusters 39
3.3.1 Dimers 39
3.3.2 Trimers 40
3.4 Effect of Plasmon Modes on SMSERS 47
3.4.1 Effect of the Spectral Lineshape 47
3.4.2 Effect of Multiple Normal Modes 49
3.5 Conclusions 54
Acknowledgment 54
References 54
4. Experimental Demonstration of Electromagnetic Mechanism of SERS and Quantitative Analysis of SERS Fluctuation Based on the Mechanism 59
Tamitake Itoh
4.1 Experimental Demonstration of the EM Mechanism of SERS 59
4.1.1 Introduction 59
4.1.2 Observations of the EM Mechanism in SERS Spectral Variations 60
4.1.3 Observations of the EM Mechanism in the Refractive Index Dependence of SERS Spectra 62
4.1.4 Quantitative Evaluation of the EM Mechanism of SERS 64
4.1.5 Summary 72
4.2 Quantitative Analysis of SERS Fluctuation Based on the EM Mechanism 72
4.2.1 Introduction 72
4.2.2 Intensity and Spectral Fluctuation in SERS and SEF 73
4.2.3 Framework for Analysis of Fluctuation in SERS and SEF 73
4.2.4 Analysis of Intensity Fluctuation in SERS and SEF 76
4.2.5 Analysis of Spectral Fluctuation in SERS and SEF 78
4.2.6 Summary 82
4.3 Conclusion 82
Acknowledgments 83
References 83
5. Single-Molecule Surface-Enhanced Raman Scattering as a Probe for Adsorption Dynamics on Metal Surfaces 89
Mai Takase, Fumika Nagasawa, Hideki Nabika and Kei Murakoshi
5.1 Introduction 89
5.2 Simultaneous Measurements of Conductance and SERS of a Single-Molecule Junction 90
5.3 SERS Observation Using Heterometallic Nanodimers at the Single-Molecule Level 96
5.4 Conclusion 101
Acknowledgments 101
References 101
6. Analysis of Blinking SERS by a Power Law with an Exponential Function 107
Yasutaka Kitahama and Yukihiro Ozaki
6.1 Introduction 107
6.2 Materials and Methods 110
&nbs
Preface xv
1. Calculation of Surface-Enhanced Raman Spectra Including Orientational and Stokes Effects Using TDDFT/Mie Theory QM/ED Method 1
George C. Schatz and Nicholas A. Valley
1.1 Introduction: Combined Quantum Mechanics/Electrodynamics Methods 1
1.2 Computational Details 3
1.3 Summary of Model Systems 4
1.4 Azimuthal Averaging 5
1.5 SERS of Pyridine: Models G, A, B, S, and V 6
1.6 Orientation Effects in SERS of Phthalocyanines 11
1.7 Two Particle QM/ED Calculations 13
1.8 Summary 15
Acknowledgment 16
References 16
2. Non-resonant SERS Using the Hottest Hot Spots of Plasmonic Nanoaggregates 19
Katrin Kneipp and Harald Kneipp
2.1 Introduction 19
2.2 Aggregates of Silver and Gold Nanoparticles and Their Hot Spots 21
2.2.1 Evaluation of Plasmonic Nanoaggregates by Vibrational Pumping due to a Non-resonant SERS Process 21
2.2.2 Probing Plasmonic Nanoaggregates by Electron Energy Loss Spectroscopy 24
2.2.3 Probing Local Fields in Hot Spots by SERS and SEHRS 25
2.3 SERS Using Hot Silver Nanoaggregates and Non-resonant NIR Excitation 26
2.3.1 SERS Signal vs. Concentration of the Target Molecule 26
2.3.2 Spectroscopic Potential of Non-resonant SERS Using the Hottest Hot Spots 30
2.4 Summary and Conclusions 31
References 32
3. Effect of Nanoparticle Symmetry on Plasmonic Fields: Implications for Single-Molecule Raman Scattering 37
Lev Chuntonov and Gilad Haran
3.1 Introduction 37
3.2 Methodology 38
3.3 Plasmon Mode Structure of Nanoparticle Clusters 39
3.3.1 Dimers 39
3.3.2 Trimers 40
3.4 Effect of Plasmon Modes on SMSERS 47
3.4.1 Effect of the Spectral Lineshape 47
3.4.2 Effect of Multiple Normal Modes 49
3.5 Conclusions 54
Acknowledgment 54
References 54
4. Experimental Demonstration of Electromagnetic Mechanism of SERS and Quantitative Analysis of SERS Fluctuation Based on the Mechanism 59
Tamitake Itoh
4.1 Experimental Demonstration of the EM Mechanism of SERS 59
4.1.1 Introduction 59
4.1.2 Observations of the EM Mechanism in SERS Spectral Variations 60
4.1.3 Observations of the EM Mechanism in the Refractive Index Dependence of SERS Spectra 62
4.1.4 Quantitative Evaluation of the EM Mechanism of SERS 64
4.1.5 Summary 72
4.2 Quantitative Analysis of SERS Fluctuation Based on the EM Mechanism 72
4.2.1 Introduction 72
4.2.2 Intensity and Spectral Fluctuation in SERS and SEF 73
4.2.3 Framework for Analysis of Fluctuation in SERS and SEF 73
4.2.4 Analysis of Intensity Fluctuation in SERS and SEF 76
4.2.5 Analysis of Spectral Fluctuation in SERS and SEF 78
4.2.6 Summary 82
4.3 Conclusion 82
Acknowledgments 83
References 83
5. Single-Molecule Surface-Enhanced Raman Scattering as a Probe for Adsorption Dynamics on Metal Surfaces 89
Mai Takase, Fumika Nagasawa, Hideki Nabika and Kei Murakoshi
5.1 Introduction 89
5.2 Simultaneous Measurements of Conductance and SERS of a Single-Molecule Junction 90
5.3 SERS Observation Using Heterometallic Nanodimers at the Single-Molecule Level 96
5.4 Conclusion 101
Acknowledgments 101
References 101
6. Analysis of Blinking SERS by a Power Law with an Exponential Function 107
Yasutaka Kitahama and Yukihiro Ozaki
6.1 Introduction 107
6.2 Materials and Methods 110
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