Surfactants and Polymers in Aqueous Solution

Krister Holmberg is Professor of Surface Chemistry and Director of Materials Science Area of Advance at Chalmers University of Technology in Göteborg (Sweden). He was awarded a PhD at Chalmers University and after gaining his doctorate, he worked as a researcher at a number of Swedish chemical companies. From 1991 to 1997 he was head of the Surface Chemistry Institute, Stockholm (Sweden). He was also adjunct professor at Göteborg University in Biotechnical Surface Chemistry and at the Royal Institute of Technology in Technical Surface and Colloid Chemistry. Professor Holmberg's current research interests include novel surfactants, organic and bioorganic reactions in organized media such as microemulsions and suspensions of mesoporous materials, and controlled delivery of active substances.

Many industrial formulations such as detergents, paints, foodstuff and cosmetics contain both surfactants and polymers and their interaction govern many of the properties. This book is unique in that it discusses the solution chemistry of both surfactants and polymers and also the interactions between the two. The book, which is based on successful courses given by the authors since 1992, is a revised and extended version of the first edition that became a market success with six reprints since 1998. Surfactants and Polymers in Aqueous Solution is broad in scope, providing both theoretical insights and practical help for those active in the area.
This book contains a thorough discussion of surfactant types and gives information of main routes of preparation. A chapter on novel surfactants has been included in the new edition. Physicochemical phenomena such as self-assembly in solution, adsorption, gel formation and foaming are discussed in detail. Particular attention is paid to the solution behaviour of surfactants and polymers containing polyoxyethylene chains. Surface active polymers are presented and their interaction with surfactants is a core topic of the book. Protein-surfactant interaction is also important and a new chapter deals with this issue. Microemulsions are treated in depth and several important application such as detergency and their use as media for chemical reactions are presented. Emulsions and the choice of emulsifier is discussed in some detail. The new edition also contains chapters on rheology and wetting.
Surfactants and Polymers in Aqueous Solution is aimed at those dealing with surface chemistry research at universities and with surfactant formulation in industry.

Preface to the Second Edition.
 
Preface to the First Edition.
 
Introduction to Surfactants.
 
Surfactant Micellization.
 
Phase Behaviour of Concentrated Surfactant Systems.
 
Physicochemical Properties of Surfactants and Polymers Containing Oxyethylene Groups.
 
Mixed Micelles.
 
Microemulsions.
 
Intermolecular Interactions.
 
Colloidal Forces.
 
Polymers in Solution.
 
Regular Solution Theory.
 
Novel Surfactants.
 
Surface Active Polymers.
 
Surfactant-Polymer Systems.
 
Surfactant-Protein Mixtures.
 
An Introduction to the Rheology of Polymer and Surfactant Solutions.
 
Surface Tension and Adsorption at the Air-Water Interface.
 
Adsorption of Surfactants at Solid Surfaces.
 
Wetting and Wetting Agents, Hydrophobization and Hydrophobizing Agents.
 
Interaction of Polymers with Surfaces.
 
Foaming of Surfactant Solutions.
 
Emulsions and Emulsifiers.
 
Microemulsions for Soil and Oil Removal.
 
Chemical Reactions in Microheterogeneous Systems.
 
Appendices.
 
Index.

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