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Fluxional Organometallic and Coordination Compounds
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Artikel-Nr:
9780470858394
Veröffentl:
2008
Erscheinungsdatum:
06.10.2008
Seiten:
344
Autor:
Marcel Gielen
Gewicht:
621 g
Format:
236x159x25 mm
Sprache:
Englisch
Beschreibung:
Marcel Gielen, Professor Emeritus, Free University of Brussels, Belgium. Member of the Editorial Board on the journal, Applied Organometallic Chemistry.
This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry.
This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.
* Provides information on some of the most relevant physical methods for studying dynamic processes
* Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications
* Connects main group, transition metal and solid state chemistry in the question for dynamics
This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.
* Provides information on some of the most relevant physical methods for studying dynamic processes
* Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications
* Connects main group, transition metal and solid state chemistry in the question for dynamics
Contributors.
Series Preface.
Preface.
1 Polyhedral Dynamics and the Jahn-Teller Effect (R. Bruce King).
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes (I. D. Gridnev and O. L. Tok).
3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR (S. Sakharov).
4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes (P. Espinet and J. A. Casares).
5 Dynamic and Kinetic Aspects of Metallodrugs by NMR (F. Li and H. Sun).
6 Dynamics by EPR: Picosecond to Microsecond Time Scales (S. Van Doorslaer and G. Jeschke).
7 1/4SR Studies of Molecular Dynamics in Organometallics (U. A. Jayasooriya).
8 Proton Dynamics in Solids: Vibrational Spectroscopy with Neutrons (F. Fillaux).
Index.
Series Preface.
Preface.
1 Polyhedral Dynamics and the Jahn-Teller Effect (R. Bruce King).
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes (I. D. Gridnev and O. L. Tok).
3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR (S. Sakharov).
4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes (P. Espinet and J. A. Casares).
5 Dynamic and Kinetic Aspects of Metallodrugs by NMR (F. Li and H. Sun).
6 Dynamics by EPR: Picosecond to Microsecond Time Scales (S. Van Doorslaer and G. Jeschke).
7 1/4SR Studies of Molecular Dynamics in Organometallics (U. A. Jayasooriya).
8 Proton Dynamics in Solids: Vibrational Spectroscopy with Neutrons (F. Fillaux).
Index.
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