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Autor: Duncan W. Bruce
ISBN-13: 9780470686065
Einband: E-Book
Seiten: 376
Sprache: Englisch
eBook Typ: PDF
eBook Format: E-Book
Kopierschutz: Adobe DRM [Hard-DRM]
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Molecular Materials

Inorganic Materials Series
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"... the book does an excellent job of puttingtogether several different classes of materials. Many common pointsemerge, and the book may facilitate the development of hybrids inwhich the qualities of the "parents" areenhanced." -Angew. Chem. Int. Ed. 2011
With applications in optoelectronics and photonics, quantuminformation processing, nanotechnology and data storage, molecularmaterials enrich our daily lives in countless ways. These materialshave properties that depend on their exact structure, the degree oforder in the way the molecules are aligned and their crystallinenature. Small, delicate changes in molecular structure can totallyalter the properties of the material in bulk.

There has been increasing emphasis on functional metal complexesthat demonstrate a wide range of physical phenomena. MolecularMaterials represents the diversity of the area, encapsulatingmagnetic, optical and electrical properties, with chapters on:
* Metal-Based Quadratic Nonlinear Optical Materials
* Physical Properties of Metallomesogens
* Molecular Magnetic Materials
* Molecular Inorganic Conductors and Superconductors
* Molecular Nanomagnets

Structured to include a clear introduction, a discussion of thebasic concepts and up-to-date coverage of key aspects, each chapterprovides a detailed review which conveys the excitement of work inthat field.

Additional volumes in the Inorganic Materials Series:

Low-Dimensional Solids | Molecular Materials | Porous Materials| Energy Materials
Inorganic Materials Preface


List of Contributors

1 Metal-Based Quadratic Nonlinear Optical Materials

Olivier Maury and Hubert Le Bozec

1.1 Introduction

1.2 Basic concepts of second order nonlinear optics

1.3 Dipolar metal complexes

1.4 Octupolar metal complexes

1.5 Switching optical nonlinearities of metal complexes

1.6 Towards the design of pre-organized materials

1.7 Conclusion


2 Physical Properties of Metallomesogens

Koen Binnemans

2.1 Introduction

2.2 Overview of Mesophases

2.3 Optical properties

2.4 Electrical properties

2.5 Magnetic properties

2.6 Conclusions


3 Molecular Magnetic Materials

Gordon T. Yee and Neil Robertson

3.1 Introduction

3.2 Basic Concepts

3.3 The Van Vleck Equation

3.4 Dimensionality of Magnetic Systems

3.5 Switchable and hybrid systems and future pespectives

3.5.1 Bistable and Switchable magnetic materials

3.5.2 Multifunctional Magnetic Materials

3.6 Summary and conclusions


4 Molecular Inorganic Conductors and Superconductors

Lydie Valade and Hisashi Tanaka

4.1 Introduction

4.2 Families of Molecular Conductors and Superconductors

4.3 Systems based on Metal Bis-Dithiolene Complexes

4.4 Towards the Application of Molecular Inorganic Conductors and Superconductors

4.5 Conclusion

4.6 Acknowledgements


5 Molecular Nanomagnets

Eric J. L. McInnes and Richard E. P. Winpenny

5.1 Introduction

5.2 A Very Brief Introduction to Magnetochemistry

5.3 Techniques

5.4 Single Molecule Magnets

5.5 Emerging Trends


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Autor: Duncan W. Bruce
ISBN-13 :: 9780470686065
ISBN: 0470686065
Verlag: John Wiley & Sons
Seiten: 376
Sprache: Englisch
Auflage 1. Auflage
Sonstiges: Ebook